Waste Recycle And Disposal Guidelines

Class 1 waste is any material that, because of its concentration or physicochemical characteristics, is considered “toxic, corrosive, flammable, a strong sensitizer or irritant, a generator of sudden pressure by decomposition, heat or other means, or may pose a substantial present or potential danger to human health or the environment when improperly processed, stored, transported, disposed of, or otherwise managed,” as further defined in 30 TAC 335.505 [Texas Administrative Code].

Class 2 waste is any material that cannot be described as hazardous, as class 1, or as class 3.

Class 3 wastes are inert and essentially insoluble materials, usually including, but not limited to, “materials such as rock, brick, glass, dirt and certain plastics and rubber, etc., that are not readily decomposable.”

Table 2.4
Waste Recycle/Disposal Guidelines

M Recycle / Disposal Class
Acids (undiluted) Disposal Haz
Acids (spent, except hydrofluoric acid) Dilute and dispose of down sink drain
Barite, finished or crude Recycle
Bentonite clays and test fluids Recycle
Biocides Disposal per MSDS 1, 2, or Haz
Bleach Dilute and dispose of down sink drain
Brines, high-density, new Reclycle
Brines, high-density, used Disposal 2
Brine/oil mixtures (emulsion testing, etc.) Disposal 1
Broken glass Disposal 2
Buffer solution Dilute and dispose of down sink drain 2
Calcium carbonate Disposal 2
Calcium chloride (solid) Disposal 2
Calcium chloride (solution) Dilute and dispose of down sink drain
Chemical spill kits Disposal per kit directions 1, 2, or Haz
Cleaning service rags Disposal 2
Freshwater test fluids Recycle
Corrosion inhibitors Corrosion inhibitors 1, 2, or Haz
Culture waste (filter media, gravel, etc.) Disposal 2
Cuttings, neat Disposal 2
Cuttings, with oil Disposal 1
Empty containers, hazardous Disposal 1
Empty containers,nonhazardous Disposal 2
Enzyme solutions Dilute and dispose of down sink drain
Filter cake, disks, and paper w/chrome-free mud Recycle
Field product samples Disposal 1, 2, or Haz
Filter cake, disks, and paper w/chrome-containing mud Disposal Haz
Freshwater test fluids Recycle
Hydrofluoric acid (handle with extreme care) Disposal Haz
Hydrogen peroxide Disposal 2
Hydroxy ethyl cellulose Disposal 2
Lignosulfonate and lignite product test muds Disposal
Mercury thermometers Disposal haz
Well-cleaning chemicals Disposal per MSDS 1, 2, or Haz
Mud additives Disposal per MSDS 1, 2, or Haz
Fluid loss control
Shale inhibitors
Shale stabilizers
Wetting agents
Mud filtrates, oil-based/synthetic-based mud Disposal 1
Mud filtrates, water-based mud Recycle
Oil, with non-OBM constituents Disposal 1
Oil, with OBM constituents required for OBM conditioning Recycle
Oil, mixed with hazardous wastes Disposal 2
Oil-based/synthetic-based mud and wash chemicals Disposal 1
Organic peroxides Disposal 2
Paper towels used to clean up brines and muds Disposal 2
Persulfates Disposal Haz
pH Buffers Dilute and dispose of down sink drain
pH test solution residuals Return to original container
Polymer slurries, mineral oil or other carrier Disposal 1
Polymers, dry Disposal 2
Potassium hydroxide (solid) Disposal Haz
Potassium hydroxide (solution) Dilute and dispose of down sink drain
Retort cooked solids (chrome-containing mud) Disposal Haz
Retort cooked solids (chrome-free mud) Disposal 2
Salt gel/attapulgite Disposal 2
Silver nitrate solution Dilute and dispose of down sink drain
Sodium carbonate (solid) Disposal Haz
Sodium carbonate (solution) Dilute and dispose of down sink drain
Sodium hydroxide (solid) Disposal Haz
Sodium hydroxide (solution) Dilute and dispose of down sink drain
Solvents, chlorinated Disposal Haz
Solvents, nonchlorinated Disposal Haz
Titration residue Dilute and dispose of down sink drain
Titration solution residue Dilute and dispose of down sink drain
Wash water, laboratory equipment and general Dilute and dispose of down sink drain
WBM spent titrations Dilute and dispose of down sink drain
WBM (Cl<20,000 ppm and oil <3%) Recycle
WBM (Cl >20,000 ppm or oil>3%) Disposal 1
WBM, chrome-free saltwater Disposal
WBM, chrome-containing Disposal
WBM, all others Disposal

OBM=oil-based mud; WBM=water-based mud; MSDS=Material Safety Data Sheet


  1. Handling Drilling Fluid Products and Cuttings

Working with drilling fluids can be hazardous. Some drilling-fluid products emit noxious or hazardous vapors that may reach levels that exceed the maximum recommended short-term or long-term safe exposure limits. Some shale and corrosion inhibitors and some oil-base mud emulsifiers tend to produce ammonia or other hazardous volatile amines, particularly in hot areas on a rig. Other products are flammable or combustible (flash point <140F), so that they too must be handled with caution. Thus, proper ventilation is vital in the mud pit areas and around the solids-control equipment.

Various mud products, brines, cleaning agents, solvents, and base oils commonly found on drill rigs are irritating or even hazardous to body tissues. Cuttings may be coated with these materials, too. Consequently, proper protective equipment should be worn for hands, body, and eyes when working around solids-control devices, even though the protective equipment may be inconvenient or uncomfortable.

  1. Drilling Fluid Product Compatibility and Storage Guidelines

Mud products and test reagents can be particularly hazardous when stored improperly. As in any well-run chemistry laboratory, materials on the rig that are chemically incompatible should be stored apart from each other, and preferably in separate spill trays (secondary containment vessels). Some general storage guidelines are given in Table 2.3. Mud products and test reagents are classified into six hazard groups, in decreasing order of hazard risk (priority)—reactive/oxidizer, toxic, flammable, acids and bases, unknown, and nonhazardous—and each group should be segregated from the others. There should be very little or no material on the rig that falls into the reactive/oxidizer category. Acids and bases, though grouped together, should be placed in separate spill trays.

Table 2.3

Hazard Classification of Chemical Reagents and Mud Products

Chemical Segregation Guidelines

Safe storage practices require that materials be separated according to chemical compatibility and hazard class. The following hazard classes should be used for segregating the waste of decreasing hazard potential. Each hazard class of chemicals should be stored in a separate secondary containment labeled with the hazard class name. The containment vessels for hazard classes containing primarily solids (e.g., nonhazardous materials) should be placed above all others. Priority 3 materials should be isolated from the flammables cabinet. The secondary containment vessel for the oxidizer hazard classes should be made of metal and sit on a metal shelf.

Hazard Class Definition Example
Water/air Materials that are potentially explosive, react violently, or generate toxic vapors when allowed to come in contact with air or water Acetyl chloride, sodium metal, potassium metal, phosphorus (red and white),inorganic solid peroxides
Oxidizers,inorganic salts Specific listed inorganic compounds that react vigorously with organic materials and/or reducing agents Inorganic liquid peroxides, chlorates, perchlorates, persulfates, nitrates, permanganates, bleach
Oxidizers,inorganic acids (liq) Inorganic liquids with pH<2 and strong

tendency to oxidize organics

Perchloric, pitric, concentrated sulfuric,

bromic, hypochlorous

Oxidizers, organic Specific ‘‘listed’’ organic compounds that react vigorously with organic materials and/or reducing agents Organic peroxides
Toxic materials, metals Materials that contain specific ‘‘listed’’

water-soluble or volatile, nonoxidizing/

nonreacting metallic compounds that are regulated at levels below a few mg/L

Metals and water-soluble compounds of

arsenic, barium, beryllium, cadmium, chromium, copper, lead, mercury,thallium (e.g., chrome lignosulfonate(CLS) and materials contamined with CLS.

Toxic materials, organic reagents Specific ‘‘listed’’ compounds whose concentrations in wastes are regulated at levels

of 0.1 to 200 mg/L

Phenol, biocides, cyanides, propargyl alcohol,

carbon disulfide

Flammable and combustible


Nonhalogenated, pourable, organic liquids

with flashpoint <140_F (classes I and II)

Acetone, xylene, toluene, methanol, most organic oils, oil-based mud, brine/oil mixtures, oily cuttings solvent wash,invert mud emulsifiers and wetting agents, some lubricants
Halogenated liquids Halogenated organic liquids, whether flammable or not Chloroform, methylene chloride
Acids, organic (liq) Organic liquids with pH<2 Acetic, butyric, formic
Acids, inorganic mineral (liq) and some concentrated


Inorganic liquids with pH<2, generally

acids and certain salts

Hydrochloric, hydrobromic, hydrofluoric,

dilute sulfuric, phosphoric, conc. brines

(low pH, e.g., bromides and iodides)

Bases, organic (liq) Organic liquids with pH>12.5 Amines, hydrazines
Bases, inorganic (liq) Inorganic liquids with pH>12.5 Ammonia, ammonium hydroxide, sodium

hydroxide, potassium hydroxide

Unclassified materials

(hazardous and


Calorimetric ampoules (ammonia and

phosphate); mercury thermometers; salt gel (attapulgite); chemical spill kits, corrosion inhibitors, field product samples, HTCE residuals, well-cleaning chemicals, some shale inhibitors, tar

Nonhazardous materials, salts,

clays, etc.

Miscellaneous materials that do not exhibit any of the hazards identified in categories 1–10, including nonoxidizing salts with 2<pH<12.5 (if in solution) Most clays; nonflammable/noncombustible/nontoxic polymers (HEC, CMC,PAC); chrome-free lignosulfonates;most empty containers;chrome-free freshwater test fluids, filter cakes, filter media, retort solids residue; solid or aqueous chlorides, formates,carbonates,acetates, dilute bromides, and iodides

3.Waste Management and Disposal

The drilling-fluid program should address environmental issues concerned with the discharge of drilling fluid, products, and removed solids. Personnel managing the solids-separation equipment must be very familiar with this part of the drilling-fluid program and have a good

understanding of governmental regulations and operator requirements. Many drilling operations have strategies in place for drilling-fluid recovery and will have established some general guidelines for the disposal of materials classified as waste. However, situations can arise that present the engineer managing the solids-control equipment with the issue of whether to discard or recycle some types of waste and how to do it. If disposal costs are not a factor, then all waste can be disposed of and treated, if necessary, onsite or sent to a processor offsite. However, if it is possible to recycle some of the products to the mud system, it may prove economical to do so [Hollier et al]. Table 2.4 contains some general guidelines approved in the state of Texas for recycling and disposing of waste from a drilling operation. Definitions used in those guidelines for hazardous, class 1, class 2, and class 3 wastes are given below. Solid waste is classified as hazardous by the U.S. Environmental Protection Agency if it meets any of the following four conditions:

. The waste exhibits ignitability, corrosivity, reactivity, or toxicity.

. The waste is specifically listed as being hazardous in one of the four tables of 40 CFR 261: [Code of Federal Regulations]

  1. Hazardous wastes from nonspecific sources (40 CFR 261.31)
  2. Hazardous wastes from specific sources (40 CFR 261.32)
  3. Acute hazardous wastes (40 CFR 261.33(e))
  4. Toxic hazardous wastes (40 CFR 261.33(f)).

. The waste is a mixture of a listed hazardous waste and a nonhazardous waste.

. The waste has been declared to be hazardous by the generator.

read more